Exciplexes of Fluorinated and Methylated Derivatives of Dibenzoylmethanatoboron Difluoride with Benzene and Toluene on the Surface of Trimethylsilylated Aerosil


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It has been shown that the introduction of electron-donating or electron-withdrawing groups in the para-position of dibenzoylmethanatoboron difluoride (DBMBF2) makes it possible to control the fluorescenсe characteristics of fluorophore exciplexes with methylbenzenes (MB). The fluorescent properties of DBMBF2/MB exciplexes at the gas–solid interface have been studied using the example of DBMBF2 adsorbed on the surface of trimethylsilylated aerosil.

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D. Ionov

Photochemistry Center, “Crystallography and Photonics” Federal Research Center, Russian Academy of Sciences

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Email: dmitriy.ionov@gmail.com
俄罗斯联邦, Moscow, 119421

V. Sazhnikov

Photochemistry Center, “Crystallography and Photonics” Federal Research Center, Russian Academy of Sciences

Email: dmitriy.ionov@gmail.com
俄罗斯联邦, Moscow, 119421

G. Yurasik

Photochemistry Center, “Crystallography and Photonics” Federal Research Center, Russian Academy of Sciences

Email: dmitriy.ionov@gmail.com
俄罗斯联邦, Moscow, 119421

A. Safonov

Photochemistry Center, “Crystallography and Photonics” Federal Research Center, Russian Academy of Sciences

Email: dmitriy.ionov@gmail.com
俄罗斯联邦, Moscow, 119421

Yu. Kononevich

Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences

Email: dmitriy.ionov@gmail.com
俄罗斯联邦, Moscow, 119991

M. Alfimov

Photochemistry Center, “Crystallography and Photonics” Federal Research Center, Russian Academy of Sciences; Moscow Institute of Physics and Technology (State University)

Email: dmitriy.ionov@gmail.com
俄罗斯联邦, Moscow, 119421; Dolgoprudny, Moscow oblast, 141701

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