Chemiluminescent Method for Determination of Rate Constants for Reactions of Triplet Aromatic Nitrenes


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It has been shown that the chemiluminescence accompanying the deoxygenation of nitrosobenzenes with triphenylphosphine can be used to measure the rate constants of reactions of the intermediates triplet nitrenes with the system components nitroso compounds and triphenylphosphine.

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V. Shamukaev

Ufa Institute of Chemistry

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Email: kinetic@anrb.ru
俄罗斯联邦, Ufa, Bashkortostan, 450054

E. Chainikova

Ufa Institute of Chemistry

Email: kinetic@anrb.ru
俄罗斯联邦, Ufa, Bashkortostan, 450054

A. Idrisova

Bashkir State Pedagogical University

Email: kinetic@anrb.ru
俄罗斯联邦, Ufa, Bashkortostan, 450000

R. Safiullin

Ufa Institute of Chemistry

Email: kinetic@anrb.ru
俄罗斯联邦, Ufa, Bashkortostan, 450054

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