Photoconductivity of film composites based on branched carbazolyl oligomers with different numbers of terminal groups


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Abstract

Peculiarities of photoconductivity of film composites based on branched carbazolyl-containing oligomers with a branching center on a silicon atom have been studied. An increase in the photocurrent and a decrease in the photoresponse time have been found in the film composites on passing to the oligomers with larger numbers of branches (from 2 to 3 and 4). It is assumed that the increase in the photoconductivity is determined by the increase in the effective mobility of the holes. A phenomenological model describing the effects observed is proposed.

About the authors

E. V. Mokrinskaya

Kiev National University

Email: ndav@univ.kiev.ua
Ukraine, Kiev, 01601

S. L. Studzinsky

Kiev National University

Email: ndav@univ.kiev.ua
Ukraine, Kiev, 01601

V. A. Pavlov

Kiev National University

Email: ndav@univ.kiev.ua
Ukraine, Kiev, 01601

N. G. Chuprina

Kiev National University

Email: ndav@univ.kiev.ua
Ukraine, Kiev, 01601

V. V. Kravchenko

Litvinenko Institute of Physical Organic Chemistry and Coal Chemistry

Email: ndav@univ.kiev.ua
Ukraine, Kiev, 02160

A. I. Marinin

National University of Food Technology

Email: ndav@univ.kiev.ua
Ukraine, Kiev, 01601

L. S. Tonkopieva

Kiev National University

Email: ndav@univ.kiev.ua
Ukraine, Kiev, 01601

I. I. Davidenko

Kiev National University

Email: ndav@univ.kiev.ua
Ukraine, Kiev, 01601

N. A. Davidenko

Kiev National University

Author for correspondence.
Email: ndav@univ.kiev.ua
Ukraine, Kiev, 01601

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