Synthesis and properties of a platinum catalyst supported on plasma chemical silicon carbide


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Abstract

A CO oxidation catalyst based on β–SiC and Pt nanoparticles has been synthesized and studied. The average size of Pt clusters on the surface of the plasma-chemical silicon carbide nanoparticles is close to 4 nm. It has been found that the rate of the CO oxidation reaction at low concentrations (100 mg/m3) in air at room temperature over the catalyst based on platinum and silicon carbide nanoparticles is 60–90 times that over a platinum black-based catalyst with a specific surface area of 30 m2/g. The Pt/SiC catalyst containing 12 wt % Pt has been found to provide the maximum CO oxidation rate.

About the authors

N. N. Vershinin

Institute of Problems of Chemical Physics

Author for correspondence.
Email: vernik@icp.ac.ru
Russian Federation, pr. Akademika Semenova 1, Chernogolovka, 142432

V. A. Bakaev

Institute of Problems of Chemical Physics

Email: vernik@icp.ac.ru
Russian Federation, pr. Akademika Semenova 1, Chernogolovka, 142432

V. I. Berestenko

Institute of Problems of Chemical Physics

Email: vernik@icp.ac.ru
Russian Federation, pr. Akademika Semenova 1, Chernogolovka, 142432

O. N. Efimov

Institute of Problems of Chemical Physics

Email: vernik@icp.ac.ru
Russian Federation, pr. Akademika Semenova 1, Chernogolovka, 142432

E. N. Kurkin

Institute of Problems of Chemical Physics; Scientific Center in Chernogolovka

Email: vernik@icp.ac.ru
Russian Federation, pr. Akademika Semenova 1, Chernogolovka, 142432; ul. Lesnaya 9, Chernogolovka, 142432

E. N. Kabachkov

Institute of Problems of Chemical Physics; Scientific Center in Chernogolovka; Ural Federal Institute

Email: vernik@icp.ac.ru
Russian Federation, pr. Akademika Semenova 1, Chernogolovka, 142432; ul. Lesnaya 9, Chernogolovka, 142432; ul. Mira 19, Yekaterinburg, 620002

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