Processes occurring during the interaction of molecular bromine with acrylamide at low temperatures and upon heating the mixture


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Abstract

It has been shown that the addition of molecular bromine to the monomer acrylamide (AA) results in the spontaneous formation of radicals. During heating the AA + Br2 mixture, the radicals initiate polymerization and bromination reactions. Beginning well below the melting point of bromine, both the reactions proceed at a noticeable rate at its melting temperature.

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D. A. Gordon

Institute of Problems of Chemical Physics

Author for correspondence.
Email: diliarag@gmail.com
Russian Federation, pr. Akademika Semenova 1, Chernogolovka, Moscow oblast, 142432

G. A. Kichigina

Institute of Problems of Chemical Physics

Email: diliarag@gmail.com
Russian Federation, pr. Akademika Semenova 1, Chernogolovka, Moscow oblast, 142432

A. I. Mikhailov

Institute of Problems of Chemical Physics

Email: diliarag@gmail.com
Russian Federation, pr. Akademika Semenova 1, Chernogolovka, Moscow oblast, 142432

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