Enviar artigo por via de e-mail Combustion mechanism of perchlorates of methyl ammonium derivatives
- Autores: Sinditskii V.P.1, Egorshev V.Y.1, Serushkin V.V.1, Chepurnoy A.O.1, Mikhaleva A.A.1
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Afiliações:
- D. I. Mendeleev University of Chemical Technology of Russia
- Edição: Volume 16, Nº 3 (2023)
- Páginas: 93-99
- Seção: Articles
- URL: https://bakhtiniada.ru/2305-9117/article/view/289636
- DOI: https://doi.org/10.30826/CE23160309
- EDN: https://elibrary.ru/PBUOBC
- ID: 289636
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Resumo
Possible reasons for the unusual dependences of the burning rates on the pressure of onium salts of perchloric acid with methylamines are considered. It is shown that combustion of perchlorates of methyl ammonium derivatives is formed from the competition of precesses in the gas and condensed phases. In the implementation of the gas-phase combustion mechanism, very large evaporation enthalpies of salts play a huge role in the stability of salt combustion. The process of salt evaporation also affects the condensed-phase mechanism through high dissociation (surface) temperatures.
Sobre autores
Valery Sinditskii
D. I. Mendeleev University of Chemical Technology of Russia
Autor responsável pela correspondência
Email: vps@muctr.ru
Doctor of Science in chemistry, professor, dean, Chemical Engineering Department
Rússia, MoscowViacheslav Egorshev
D. I. Mendeleev University of Chemical Technology of Russia
Email: egorshev@yahoo.com
senior lecturer, Department of Chemistry and Technology of Organic Nitrogen Compounds
Rússia, MoscowValery Serushkin
D. I. Mendeleev University of Chemical Technology of Russia
Email: serushkin.v.v@muctr.ru
Candidate of Science in technology, professor, Department of Chemistry and Technology of Organic Nitrogen Compounds
Rússia, MoscowAleksey Chepurnoy
D. I. Mendeleev University of Chemical Technology of Russia
Email: chepurnoi.a.o@muctr.ru
engineer, Department of Chemistry and Technology of Organic Nitrogen Compounds
Rússia, MoscowAlena Mikhaleva
D. I. Mendeleev University of Chemical Technology of Russia
Email: mixal1996@yandex.ru
student, Department of Chemistry and Technology of Organic Nitrogen Compounds
Rússia, MoscowBibliografia
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