Using Low-Temperature Molten Dialkylimidazole Salts in the Catalytic Reactions of Alkylation and Hydrodechlorination


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The possibility of preparing a mixture of 1,3-dialkylimidazole salts from commercially available reagents via multicomponent condensation is considered. The main factors affecting the yield of the target product, and the experimental data needed for scaling up the process, are discussed. It is shown that the prepared mixtures are close in some key properties (e.g., viscosity at different temperatures, heat capacity) to the pure salts. The possibility of using the prepared salts as solvents for catalytic hydrodechlorination and catalyst components for the alkylation of aromatic compounds is demonstrated.

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A. Klimenko

Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences; Volgograd Branch, Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences

编辑信件的主要联系方式.
Email: klimenko@catalysis.ru
俄罗斯联邦, Novosibirsk, 630090; Volgograd, 400097

S. Prikhod’ko

Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences

Email: klimenko@catalysis.ru
俄罗斯联邦, Novosibirsk, 630090

A. Beskopyl’nyi

Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences; Volgograd Branch, Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences

Email: klimenko@catalysis.ru
俄罗斯联邦, Novosibirsk, 630090; Volgograd, 400097

I. Tertishnikov

Volgograd Branch, Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences

Email: klimenko@catalysis.ru
俄罗斯联邦, Volgograd, 400097

N. Adonin

Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences

Email: klimenko@catalysis.ru
俄罗斯联邦, Novosibirsk, 630090

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