Some Peculiarities of the Reduction of Di- and Trichlorocyclopentenones


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Abstract

The hydrogenation of 5-allyl- and 5-(2-methylbut-3-en-2-yl)-2,3,5-trichlorocyclopentenones in methanol in the presence of 10% Pd/C is accompanied by exhaustive dechlorination with the formation of 3-propyl- and 3-(2-methylbutan-2-yl)cyclopentane-1,2,4-triones.

About the authors

V. A. Egorov

Ufa Institute of Chemistry, Ufa Federal Research Center

Email: bioreg@anrb.ru
Russian Federation, pr. Oktyabrya 71, Ufa, Bashkortostan, 450054

L. S. Khasanova

Ufa Institute of Chemistry, Ufa Federal Research Center

Email: bioreg@anrb.ru
Russian Federation, pr. Oktyabrya 71, Ufa, Bashkortostan, 450054

F. A. Gimalova

Ufa Institute of Chemistry, Ufa Federal Research Center

Author for correspondence.
Email: bioreg@anrb.ru
Russian Federation, pr. Oktyabrya 71, Ufa, Bashkortostan, 450054

I. A. Zagreeva

Ufa Institute of Chemistry, Ufa Federal Research Center

Email: bioreg@anrb.ru
Russian Federation, pr. Oktyabrya 71, Ufa, Bashkortostan, 450054

M. S. Miftakhov

Ufa Institute of Chemistry, Ufa Federal Research Center

Email: bioreg@anrb.ru
Russian Federation, pr. Oktyabrya 71, Ufa, Bashkortostan, 450054

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