Email this article Synthesis of 1-, 2-Methoxy-, 1,3-Dimethoxyadamantanes And 1-, 4-Methoxydiadamantanes by Reaction of Adamantyl and Diadamantyl Halides with Dimethyl Carbonate in the Presence of Zeolite Catalysts
- Authors: Khusnutdinov R.I.1, Shchadneva N.A.1, Mayakova Y.Y.1
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Affiliations:
- Institute of Petrochemistry and Catalysis of the Russian Academy of Scientists
- Issue: Vol 54, No 11 (2018)
- Pages: 1728-1730
- Section: Short Communications
- URL: https://bakhtiniada.ru/1070-4280/article/view/219451
- DOI: https://doi.org/10.1134/S1070428018110180
- ID: 219451
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Abstract
1-, 2-Methoxy-, 1,3-dimethoxyadamantane, and 1-, 4-methoxydiadamantane were prepared by the reaction of adamantyl and diadamantyl halides with dimethyl carbonate in the presence of zeolite catalysts NiHY or FeHY free of binders. Optimum ratio of catalysts and reagents were found and the reaction conditions for the selective synthesis of methoxyadamantanoids were developed.
About the authors
R. I. Khusnutdinov
Institute of Petrochemistry and Catalysis of the Russian Academy of Scientists
Email: inklab4@gmail.com
Russian Federation, pr. Oktyabrya 141, Ufa, Bashkortostan, 450075
N. A. Shchadneva
Institute of Petrochemistry and Catalysis of the Russian Academy of Scientists
Email: inklab4@gmail.com
Russian Federation, pr. Oktyabrya 141, Ufa, Bashkortostan, 450075
Yu. Yu. Mayakova
Institute of Petrochemistry and Catalysis of the Russian Academy of Scientists
Author for correspondence.
Email: inklab4@gmail.com
Russian Federation, pr. Oktyabrya 141, Ufa, Bashkortostan, 450075
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