Formation of Bi1−xCaxFeO3−δ Nanocrystals via Glycine-Nitrate Combustion


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The features of the formation of nanocrystals in the BiFeO3–CaFeO3 system via glycine-nitrate combustion were studied. The crystallite size of the bismuth orthoferrite-based solid solutions (20–45 nm), as well as their particle size, were found to depend on the calcium content. The formation processes were activated in the temperature range corresponding to the melting of the surface (nonautonomous) phase.

作者简介

N. Lomanova

Ioffe Institute

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Email: natus@mail.ioffe.ru
俄罗斯联邦, ul. Politekhnicheskaya 26, St. Petersburg, 194021

M. Tomkovich

Ioffe Institute

Email: natus@mail.ioffe.ru
俄罗斯联邦, ul. Politekhnicheskaya 26, St. Petersburg, 194021

A. Osipov

Grebenshchikov Institute of Silicate Chemistry

Email: natus@mail.ioffe.ru
俄罗斯联邦, St. Petersburg

V. Ugolkov

Grebenshchikov Institute of Silicate Chemistry

Email: natus@mail.ioffe.ru
俄罗斯联邦, St. Petersburg

D. Danilovich

St. Petersburg State Institute of Technology (Technical University)

Email: natus@mail.ioffe.ru
俄罗斯联邦, St. Petersburg

V. Panchuk

St. Petersburg State Institute of Technology (Technical University); St. Petersburg State University

Email: natus@mail.ioffe.ru
俄罗斯联邦, St. Petersburg; St. Petersburg

V. Semenov

St. Petersburg State University; Institute of Analytical Instrumentation

Email: natus@mail.ioffe.ru
俄罗斯联邦, St. Petersburg; St. Petersburg

V. Gusarov

Ioffe Institute

Email: natus@mail.ioffe.ru
俄罗斯联邦, ul. Politekhnicheskaya 26, St. Petersburg, 194021

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