Electrophilic Catalysis in the Synthesis of Aryl Methyl- and Phenylphosphonochloridates

E. I. Goryunov; I. B. Goryunova; G. N. Molchanova; I. Yu. Kudryavtsev; T. V. Baulina; A. A. Khodak; T. V. Strelkova; V. K. Brel

doi:10.1134/S1070363218090025

Electrophilic Catalysis in the Synthesis of Aryl Methyl- and Phenylphosphonochloridates

Autores: Goryunov E.I.¹, Goryunova I.B.¹, Molchanova G.N.¹, Kudryavtsev I.Y.¹, Baulina T.V.¹, Khodak A.A.¹, Strelkova T.V.¹, Brel V.K.¹
Afiliações:
1. Nesmeyanov Institute of Organoelement Compounds
Edição: Volume 88, Nº 9 (2018)
Páginas: 1776-1779
Seção: Article
URL: https://bakhtiniada.ru/1070-3632/article/view/222397
DOI: https://doi.org/10.1134/S1070363218090025
ID: 222397

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Resumo

The reaction of methyl- and phenylphosphonic dichlorides with phenols in the presence of anhydrous magnesium chloride as catalyst or magnesium metal as precatalyst provides a simple, efficient, and practical method of synthesis of the corresponding aryl methyl- and phenylphosphonochloridates.