Отправить статью по E-mail Effect of solvent on the crystal structures of copper(II) complexes based on 4′-(4-methoxyphenyl)-2,2′:6′,2″-terpyridine and 4′-(3-chlorophenyl)-2,2′:6′,2″-terpyridine
- Авторы: Fu W.W.1, Cheng Q.W.1, Wang H.Y.1, He F.Z.1, Liu Y.1, Zhang F.X.1
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Учреждения:
- Key Laboratory of Functional Organometallic Materials of Hunan Province College, Department of Chemistry and Materials Science
- Выпуск: Том 43, № 8 (2017)
- Страницы: 547-558
- Раздел: Article
- URL: https://bakhtiniada.ru/1070-3284/article/view/213492
- DOI: https://doi.org/10.1134/S1070328417080024
- ID: 213492
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Аннотация
Four homoleptic copper(II) complexes, [Cu(Meophtpy)2](ClO4)2 (Meophtpy = 4′-(4-methoxylphenyl)- 2,2′:6′,2″-terpyridine) (I), [Cu(Meophtpy)2](ClO4)2 · 2H2O (II), [Cu2(m-Clphtpy)4](ClO4)4 (m-ClPhtpy = 4′-(3-chlorophenyl)-2,2′:6′,2″-terpyridine) (III), and [Cu2(m-ClPhtpy)4](ClO4)4 (IV) have been synthesized by hydrothermal methods and characterized by IR, elemental analysis and single crystal X-ray diffraction (CIF files CCDC nos. 963375 (I), 885457 (II), 963377 (III), and 963376 (IV)). Complex II is a polymorph of I and complex IV is a polymorph of III. All these complexes are obtained with 95% ethanol solution or 50% ethanol solution and the solvent control on the crystallization are obviously found. In all complexes, the face-to-face interactions between pyridyl rings or phenyl rings facilitate the construction of 3D network in the crystal in addition to hydrogen bonds. The fluorescence properties of these complexes have been investigated.
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W. Fu
Key Laboratory of Functional Organometallic Materials of Hunan Province College, Department of Chemistry and Materials Science
Автор, ответственный за переписку.
Email: w.w.fu@hotmail.com
Китай, Hengyang, 421008
Q. Cheng
Key Laboratory of Functional Organometallic Materials of Hunan Province College, Department of Chemistry and Materials Science
Email: w.w.fu@hotmail.com
Китай, Hengyang, 421008
H. Wang
Key Laboratory of Functional Organometallic Materials of Hunan Province College, Department of Chemistry and Materials Science
Email: w.w.fu@hotmail.com
Китай, Hengyang, 421008
F. He
Key Laboratory of Functional Organometallic Materials of Hunan Province College, Department of Chemistry and Materials Science
Email: w.w.fu@hotmail.com
Китай, Hengyang, 421008
Y. Liu
Key Laboratory of Functional Organometallic Materials of Hunan Province College, Department of Chemistry and Materials Science
Email: w.w.fu@hotmail.com
Китай, Hengyang, 421008
F. Zhang
Key Laboratory of Functional Organometallic Materials of Hunan Province College, Department of Chemistry and Materials Science
Email: w.w.fu@hotmail.com
Китай, Hengyang, 421008
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