Email this article Mononuclear pivalates of metals of the first transition series
- Authors: Ovcharenko V.I.1, Fursova E.Y.1, Romanenko G.V.1
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Affiliations:
- International Tomography Center, Siberian Branch
- Issue: Vol 42, No 9 (2016)
- Pages: 584-590
- Section: Article
- URL: https://bakhtiniada.ru/1070-3284/article/view/213360
- DOI: https://doi.org/10.1134/S1070328416090049
- ID: 213360
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Abstract
The synthesis and structures of mononuclear Ni(II), Co(II), Mn(II), and Cu(II) pivalates isolated as complex salts NBu4[M(Piv)3] ((NBu4)+ is tetrabutylammonium cation, Piv– is pivalate anion) and polynuclear complexes [Ni6(L)2(HL)2(Piv)6(HPiv)8], (NBu4)2[Co4(Piv)8(AcO)2(H2O)4], NBu4[Co2(Piv)5(H2O)2], and (NBu4)2[Cu4(Piv)8(AcO)2(H2O)2] (L2–, HL–, and AcO– is lactic acid dianion, lactic acid monoanion, and acetate anion, respectively) are discussed. The formation of the compounds is detected during the development of the synthesis of NBu4[M(Piv)3].
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About the authors
V. I. Ovcharenko
International Tomography Center, Siberian Branch
Author for correspondence.
Email: Victor.Ovcharenko@tomo.nsc.ru
Russian Federation, Novosibirsk, 630090
E. Yu. Fursova
International Tomography Center, Siberian Branch
Email: Victor.Ovcharenko@tomo.nsc.ru
Russian Federation, Novosibirsk, 630090
G. V. Romanenko
International Tomography Center, Siberian Branch
Email: Victor.Ovcharenko@tomo.nsc.ru
Russian Federation, Novosibirsk, 630090
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