Synthesis of 5-amino-6-nitro-1,2,3,4-tetrazine 1,3-dioxide

A. A. Guskov; M. S. Klenov; A. M. Churakov; V. A. Tartakovsky

doi:10.1007/s11172-016-1650-2

Synthesis of 5-amino-6-nitro-1,2,3,4-tetrazine 1,3-dioxide

作者: Guskov A.A.¹, Klenov M.S.¹, Churakov A.M.¹, Tartakovsky V.A.¹
隶属关系:
1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
期: 卷 65, 编号 11 (2016)
页面: 2763-2765
栏目: Brief Communications
URL: https://bakhtiniada.ru/1066-5285/article/view/239475
DOI: https://doi.org/10.1007/s11172-016-1650-2
ID: 239475

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详细

5-Amino-(tert-butyl-NNO-azoxy)-1,2,3,4-tetrazine 1,3-dioxide reacts with nitronium tetra-fluoroborate to give 5-amino-6-nitro-1,2,3,4-tetrazine 1,3-dioxide. This compound is of interest as a new energetic material. A plausible reaction mechanism involves electrophilic substitution of the tert-butyl-NNO-azoxy group by the nitro group.