Structure control of heterometallic Li2Co2 metal core in pivalate clusters by varying apical ligands


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Based on the heterometallic fragment {Li2Co2(Piv)6}, a new complex [(terpy)2Li2Co2(Piv)6] (1) was obtained, in which the terminal cobalt atoms coordinate the 2,2’:6’,2″-terpyridine (terpy) molecules. The metal core of the molecule is a Co—Li—Li—Co chain, the metal atoms in which are bonded between each other by the pairs of carboxylate bridges.

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A. Sidorov

N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: mkiskin@igic.ras.ru
俄罗斯联邦, 31 Leninsky prosp., Moscow, 119991

M. Kiskin

N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

编辑信件的主要联系方式.
Email: mkiskin@igic.ras.ru
俄罗斯联邦, 31 Leninsky prosp., Moscow, 119991

G. Aleksandrov

N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: mkiskin@igic.ras.ru
俄罗斯联邦, 31 Leninsky prosp., Moscow, 119991

I. Eremenko

N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: mkiskin@igic.ras.ru
俄罗斯联邦, 31 Leninsky prosp., Moscow, 119991

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