Structure control of heterometallic Li2Co2 metal core in pivalate clusters by varying apical ligands
- 作者: Sidorov A.A.1, Kiskin M.A.1, Aleksandrov G.G.1, Eremenko I.L.1
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隶属关系:
- N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
- 期: 卷 65, 编号 11 (2016)
- 页面: 2754-2756
- 栏目: Brief Communications
- URL: https://bakhtiniada.ru/1066-5285/article/view/239463
- DOI: https://doi.org/10.1007/s11172-016-1647-x
- ID: 239463
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详细
Based on the heterometallic fragment {Li2Co2(Piv)6}, a new complex [(terpy)2Li2Co2(Piv)6] (1) was obtained, in which the terminal cobalt atoms coordinate the 2,2’:6’,2″-terpyridine (terpy) molecules. The metal core of the molecule is a Co—Li—Li—Co chain, the metal atoms in which are bonded between each other by the pairs of carboxylate bridges.
作者简介
A. Sidorov
N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: mkiskin@igic.ras.ru
俄罗斯联邦, 31 Leninsky prosp., Moscow, 119991
M. Kiskin
N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
编辑信件的主要联系方式.
Email: mkiskin@igic.ras.ru
俄罗斯联邦, 31 Leninsky prosp., Moscow, 119991
G. Aleksandrov
N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: mkiskin@igic.ras.ru
俄罗斯联邦, 31 Leninsky prosp., Moscow, 119991
I. Eremenko
N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: mkiskin@igic.ras.ru
俄罗斯联邦, 31 Leninsky prosp., Moscow, 119991
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