Crystal structure of new carboxylate phosphabetaines and phosphonium salts conjugated with them

Yu. V. Bakhtiyarova; A. F. Aksunova; I. V. Galkina; V. I. Galkin; O. A. Lodochnikova; O. N. Kataeva

doi:10.1007/s11172-016-1454-4

Crystal structure of new carboxylate phosphabetaines and phosphonium salts conjugated with them

作者: Bakhtiyarova Y.V.¹, Aksunova A.F.¹, Galkina I.V.¹, Galkin V.I.¹, Lodochnikova O.A.², Kataeva O.N.²
隶属关系:
1. A. M. Butlerov Chemical Institute of Kazan (Volga Region) Federal University
2. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
期: 卷 65, 编号 5 (2016)
页面: 1313-1318
栏目: Full Articles
URL: https://bakhtiniada.ru/1066-5285/article/view/238195
DOI: https://doi.org/10.1007/s11172-016-1454-4
ID: 238195

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Earlier unknown crystalline forms of three carboxylate phosphabetaines and conjugated with them phosphonium salts differing by β substituent with respect to the carboxylate group were studied. The structure of studied compounds in crystal is determined by intermolecular electrostatic interactions. This leads to the trans arrangement of the carboxylate and the phosphonium groups.