Отправить статью по E-mail Oxidation of 2,3,6-trimethylphenol to 2,3,5-trimethyl-1,4-benzoquinon over binary xerogels TiO2—SiO2 in the three-phase system
- Авторы: Mikushina Y.V.1, Shishmakov A.B.1, Petro L.A.1
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Учреждения:
- I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences
- Выпуск: Том 66, № 4 (2017)
- Страницы: 677-682
- Раздел: Full Articles
- URL: https://bakhtiniada.ru/1066-5285/article/view/240416
- DOI: https://doi.org/10.1007/s11172-017-1791-y
- ID: 240416
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Аннотация
The technique of synthesis of 2,3,5-trimethyl-1,4-benzoquinon via catalytic oxidation of 2,3,6-trimethylphenol in H2O2—H2O—PhCH3 system with vibrational stirring is developed. Xerogels TiO2 and TiO2—SiO2 were used as catalysts in the process. The effect of physicochemical properties of xerogels on the course and characteristics of oxidation is studied.
Об авторах
Yu. Mikushina
I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences
Автор, ответственный за переписку.
Email: Mikushina@ios.uran.ru
Россия, 22/20 ul. S. Kovalevskoy, Ekaterinburg, 620041
A. Shishmakov
I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences
Email: Mikushina@ios.uran.ru
Россия, 22/20 ul. S. Kovalevskoy, Ekaterinburg, 620041
L. Petro
I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences
Email: Mikushina@ios.uran.ru
Россия, 22/20 ul. S. Kovalevskoy, Ekaterinburg, 620041
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