Effect of medium acidity on the efficiency of oxidation of 2,4,6-trinitrotoluene to 2,4,6-trinitrobenzoic acid

Аннотация

An effect of boric acid additives on oxidation of 2,4,6-trinitrotoluene (TNT) to 2,4,6-trinitrobenzoic acid (TNBA) with chromic anhydride in concentrated (96—100%) H₂SO₄ has been studied. In the presence of tetrahydrosulfatoboric acid HB(HSO₄)₄ formed in situ (up to 5 mol.%) or added as a preliminary prepared solution (up to 1 mol. %), TNT is selectively oxidized to TNBA in the yields up to 95—99%. The mechanism including formation of TNT dication as a key step of its oxidation at the methyl group has been suggested.