Email this article Three-dimensional copper(II) carboxylates based on 4,4′,4″-benzene-1,3,5-triyltris(benzoic acid)
- Authors: Zavakhina M.S.1,2, Samsonenko D.G.1,2, Dybtsev D.N.1,2, Fedin V.P.1,2
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Affiliations:
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences
- Novosibirsk State University
- Issue: Vol 67, No 1 (2018)
- Pages: 36-44
- Section: Article
- URL: https://bakhtiniada.ru/1066-5285/article/view/241898
- DOI: https://doi.org/10.1007/s11172-018-2034-6
- ID: 241898
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Abstract
The homochiral coordination polymers [Cu4(CH3OH)(H2O)4(Hbtb)(S-mal)2]•4H2O and [Cu4(CH3OH)(H2O)4(Hbtb)(R-mal)2]•4H2O were synthesized by heating S- or R-malic acid (H3mal), 4,4′,4″-benzene-1,3,5-triyltris(benzoic acid) (H3btb), and copper(II) acetate in an aqueous methanolic solution. The reaction with copper(II) nitrate in aqueous dioxane afforded the coordination framework [Cu6(C4H8O2)3(H2O)3(btb)4]•4C4H8O2•10H2O, which does not contain chiral ligands. The compositions and crystal structures of the new compounds were determined by single-crystal X-ray diffraction and confirmed by X-ray powder diffraction, IR spectroscopy, thermogravimetric and elemental analysis.
About the authors
M. S. Zavakhina
Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences; Novosibirsk State University
Email: cluster@niic.nsc.ru
Russian Federation, 3 prosp. Akad. Lavrentieva, Novosibirsk, 630090; 2 ul. Pirogova, Novosibirsk, 630090
D. G. Samsonenko
Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences; Novosibirsk State University
Email: cluster@niic.nsc.ru
Russian Federation, 3 prosp. Akad. Lavrentieva, Novosibirsk, 630090; 2 ul. Pirogova, Novosibirsk, 630090
D. N. Dybtsev
Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences; Novosibirsk State University
Email: cluster@niic.nsc.ru
Russian Federation, 3 prosp. Akad. Lavrentieva, Novosibirsk, 630090; 2 ul. Pirogova, Novosibirsk, 630090
V. P. Fedin
Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences; Novosibirsk State University
Author for correspondence.
Email: cluster@niic.nsc.ru
Russian Federation, 3 prosp. Akad. Lavrentieva, Novosibirsk, 630090; 2 ul. Pirogova, Novosibirsk, 630090
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