Email this article First example of the synthesis of S,O-macroheterocycle based on 2(5H)-furanone and 2,2´-oxydiethanethiol
- Authors: Kurbangalieva A.R.1, Hoang L.T.1, Lodochnikova O.A.2, Kuzmicheva M.Y.1, Pradipta A.R.3, Tanaka K.1,3, Chmutova G.A.1
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Affiliations:
- A. M. Butlerov Institute of Chemistry of Kazan (Volga Region) Federal University
- A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
- Biofunctional Synthetic Chemistry Laboratory, RIKEN
- Issue: Vol 65, No 5 (2016)
- Pages: 1278-1284
- Section: Full Articles
- URL: https://bakhtiniada.ru/1066-5285/article/view/238126
- DOI: https://doi.org/10.1007/s11172-016-1448-2
- ID: 238126
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Abstract
A base-catalyzed reaction of 3,4-dichloro-5-methoxy- and 3,4-dichloro-5-ethoxy-2(5H)-furanones with 2,2´-oxydiethanethiol gave thiols and bis-thioethers of 2(5H)-furanone series. A new S,O-macroheterocyclic compound containing a 18-membered oxathiamacrocycle and two 2(5H)-furanone fragments was synthesized based on the thiols in an aqueous solution of potassium hydroxide, which was characterized by X-ray diffraction.
About the authors
A. R. Kurbangalieva
A. M. Butlerov Institute of Chemistry of Kazan (Volga Region) Federal University
Author for correspondence.
Email: Almira.Kurbangalieva@kpfu.ru
Russian Federation, 18 ul. Kremlevskaya, Kazan, 420008
L. T. Hoang
A. M. Butlerov Institute of Chemistry of Kazan (Volga Region) Federal University
Email: Almira.Kurbangalieva@kpfu.ru
Russian Federation, 18 ul. Kremlevskaya, Kazan, 420008
O. A. Lodochnikova
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Email: Almira.Kurbangalieva@kpfu.ru
Russian Federation, 8 ul. Akad. Arbuzova, Kazan, 420088
M. Yu. Kuzmicheva
A. M. Butlerov Institute of Chemistry of Kazan (Volga Region) Federal University
Email: Almira.Kurbangalieva@kpfu.ru
Russian Federation, 18 ul. Kremlevskaya, Kazan, 420008
A. R. Pradipta
Biofunctional Synthetic Chemistry Laboratory, RIKEN
Email: Almira.Kurbangalieva@kpfu.ru
Japan, 2-1, Hirosawa, Wako-shi, Saitama, 351-0198
K. Tanaka
A. M. Butlerov Institute of Chemistry of Kazan (Volga Region) Federal University; Biofunctional Synthetic Chemistry Laboratory, RIKEN
Email: Almira.Kurbangalieva@kpfu.ru
Russian Federation, 18 ul. Kremlevskaya, Kazan, 420008; 2-1, Hirosawa, Wako-shi, Saitama, 351-0198
G. A. Chmutova
A. M. Butlerov Institute of Chemistry of Kazan (Volga Region) Federal University
Email: Almira.Kurbangalieva@kpfu.ru
Russian Federation, 18 ul. Kremlevskaya, Kazan, 420008
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