Email this article A novel type of catalysts for asymmetric oxidative coupling of 2-naphthol
- Authors: Larionov V.A.1, Peregudova S.M.1, Maleev V.I.1, Belokon Y.N.1
-
Affiliations:
- A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
- Issue: Vol 65, No 3 (2016)
- Pages: 685-688
- Section: Full Articles
- URL: https://bakhtiniada.ru/1066-5285/article/view/237453
- DOI: https://doi.org/10.1007/s11172-016-1356-5
- ID: 237453
Cite item
Open Access
Access granted
Subscription Access
Abstract
Stereochemically inert, positively charged chiral octahedral complexes of CoIII and CrIII were used as catalysts for asymmetric oxidative coupling of 2-naphthol. The reaction product 1,1´-bi-2-naphthol was produced with a yield of up to 74% and enantiomeric excess of up to 22%. The reduction and oxidation potentials of a series of CoIII and CrIII cationic complexes were measured.
About the authors
V. A. Larionov
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: yubel@ineos.ac.ru
Russian Federation, 28 ul. Vavilova, Moscow, 119991
S. M. Peregudova
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: yubel@ineos.ac.ru
Russian Federation, 28 ul. Vavilova, Moscow, 119991
V. I. Maleev
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: yubel@ineos.ac.ru
Russian Federation, 28 ul. Vavilova, Moscow, 119991
Yu. N. Belokon
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Author for correspondence.
Email: yubel@ineos.ac.ru
Russian Federation, 28 ul. Vavilova, Moscow, 119991
Supplementary files
