A Giant Frequency Shift in the Raman Spectrum of Water Adsorbed on a Metallic Silver Surface


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Abstract

The Raman spectrum of water adsorbed on a metallic silver surface reveals an anomalously large shift of the vibrational frequency as compared to that in the bulk. The results are compared to data reported by other researchers, and possible interpretations of the observed phenomenon are discussed.

About the authors

M. E. Kompan

Ioffe Physical Technical Institute

Author for correspondence.
Email: kompan@mail.ioffe.ru
Russian Federation, St. Petersburg, 194021

V. G. Malyshkin

Ioffe Physical Technical Institute

Email: kompan@mail.ioffe.ru
Russian Federation, St. Petersburg, 194021

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