Catalytic transformations of fluids


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Fluids play a very important role in processes of the chemical and physical evolution of crustal and mantle rocks. The influence of certain rocks on chemical reactions between fluid components is studied. Experimental results of the catalytic activity of serpentinite, ophitic gabbro, and lizardite–antigorite asbestos relative to vapor conversion of methane (CH4) have been obtained with the formation of syngas at atmospheric pressure and temperatures up to 850°C. Such transformations are assumed to be able to take place under natural conditions in fluid systems that accompany massifs of seabed ultrabasic rocks, as well as kimberlite pipes. Proceeding from the studies performed, options of the practical use of various crustal rocks as catalysts of fluid transformations have been proposed. The experimental results confirm the initial theses of the authors’ concept with respect to the role of heterogeneous–catalytic mechanisms of transformations of fluids in the Earth’s crust.

作者简介

V. Barelko

Institute of Problems of Chemical Physics

Email: maxim1968@mail.ru
俄罗斯联邦, Chernogolovka, Moscow oblast

O. Safonov

Institute of Experimental Mineralogy

Email: maxim1968@mail.ru
俄罗斯联邦, Chernogolovka, Moscow oblast

N. Bykova

Institute of Problems of Chemical Physics

Email: maxim1968@mail.ru
俄罗斯联邦, Chernogolovka, Moscow oblast

L. Bykov

Institute of Problems of Chemical Physics

Email: maxim1968@mail.ru
俄罗斯联邦, Chernogolovka, Moscow oblast

V. Dorokhov

Institute of Problems of Chemical Physics

Email: maxim1968@mail.ru
俄罗斯联邦, Chernogolovka, Moscow oblast

M. Kuznetsov

All-Russia Research Institute on Problems of Civil Defense and Emergencies of the Emergency Control Ministry of Russia (Federal Science and High Technology Center)

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Email: maxim1968@mail.ru
俄罗斯联邦, Moscow

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