Production of silicon carbide from microsilica waste by reduction with lignite semicoke

详细

Silicon carbide may be produced from fine-grain batch consisting of two main components: microsilica waste; and semicoke obtained from Berezovsk lignite (Kansko-Achinsk Basin). The physicochemical properties of the silicon carbide are certified in the present work. Two forms of microsilica are considered: (1) microsilica formed in the production of silicon (containing 93.41–95.33% SiO₂; 1.96–3.28% C_free; 0.30–0.34% Si_free; and 1.25–1.45% CaO + Fe₂O₃ + MnO); (2) microsilica formed in the production of high-silica ferrosilicon: (containing 91.72–93.63% SiO₂; 0.56–1.18% C_free; 0.18–0.20% Si_free; and 1.38–2.32% CaO + Fe₂O₃ + MnO). Its specific surface is 21000–24000 m²/kg. The microsilica is inclined to form spherical aggregates measuring 200–800 nm. The aggregates consist of spherical particles ranging in size from 30 to 100 nm. The lignite semicoke contains 94.05% carbon, 9.2% ash, 0.2% sulfur, and 0.007% phosphorus; its specific surface is 264000 m²/kg. The composition of the silicon carbide is investigated, along with its specific surface; the size and shape of the carbide particles are determined. In both cases, the predominant phase is cubic silicon carbide (β-SiC), with an accompanying glassy phase consisting of silicates of calcium, magnesium, and iron. When the batch containing microsilica from ferrosilicon production, the silicon carbide is accompanied by α iron. In synthesis at 1923 and 1973 K for 50 and 90 min, respectively, polymorphic conversion of β-SiC to α-SiC_p is observed. The content of silicon carbide in the products is 82.52–84.90%. Chemical enrichment of silicon carbide proves expedient. The optimal enrichment conditions are as follows: the action of hydrochloric acid (concentration no less than 35%) at 353 K for 3 h, with a 1:2 solid/liquid ratio. The enrichment characteristics are as follows: the content of silicon carbide in the products is 90.42–91.10%; and 87–95% of the impurities (metal oxides and iron) are removed. The silicon carbide is obtained as micropowder consisting of irregular particles (size 0.2–1.0 μm) with specific surface 8000–9000 m²/kg.