The effect of crystallization on the Tb 3+  emission parameters in a solution of a terbium(III) complex with tetra-1,3-diketone calix[ 4 ]arene

D.V. Lapaev; Лапаев Д. В.; V. G. Nikiforov; Никифоров В. Г.; S. N. Sudakova; Судакова С. Н.; S. N. Podyachev; Подъячев С. Н.

doi:10.31857/S0367676523702964

The effect of crystallization on the Tb³⁺ emission parameters in a solution of a terbium(III) complex with tetra-1,3-diketone calix[4]arene

作者: Lapaev D.¹, Nikiforov V.G.¹, Sudakova S.N.², Podyachev S.N.²
隶属关系:
1. Zavoisky Physical-Technical Institute, Federal Research Center “Kazan Scientific Center of the Russian Academy of Sciences”
2. Arbuzov Institute of Organic and Physical Chemistry, Federal Research Center “Kazan Scientific Center of the Russian Academy of Sciences”
期: 卷 87, 编号 12 (2023)
页面: 1719-1723
栏目: Articles
URL: https://bakhtiniada.ru/0367-6765/article/view/232530
DOI: https://doi.org/10.31857/S0367676523702964
EDN: https://elibrary.ru/QTYFNE
ID: 232530

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详细

An abrupt lengthening (from 295 to 684 μs) of the luminescence decay time of Tb³⁺ ions in a solution of a terbium(III) complex with tetra-1,3-diketone calix[4]arene in the region of the solution crystallization temperature (212 K) was found. This fact indicates a significant sensitivity of the complex to the structure of the local environment, which can be used both for spectroscopic purposes and for remote monitoring of the phase state of the medium.

关键词

calix[4]arene, 1,3-diketone, Tb³⁺ ion, terbium(III) complex, temperature sensitivity of luminescence parameters, crystallization

作者简介

D.V. Lapaev

Zavoisky Physical-Technical Institute, Federal Research Center “Kazan Scientific Center of the Russian Academy of Sciences”

编辑信件的主要联系方式.
Email: d_lapaev@mail.ru
Russia, 420029, Kazan

V. Nikiforov

Zavoisky Physical-Technical Institute, Federal Research Center “Kazan Scientific Center of the Russian Academy of Sciences”

Email: d_lapaev@mail.ru
Russia, 420029, Kazan

S. Sudakova

Arbuzov Institute of Organic and Physical Chemistry, Federal Research Center “Kazan Scientific Center
of the Russian Academy of Sciences”

Email: d_lapaev@mail.ru
Russia, 420088, Kazan

S. Podyachev

Arbuzov Institute of Organic and Physical Chemistry, Federal Research Center “Kazan Scientific Center
of the Russian Academy of Sciences”

Email: d_lapaev@mail.ru
Russia, 420088, Kazan

参考

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