Adducts of Sterically Hindered Tellurium Catecholate with N-Methylpyrrolidone

P. A. Petrov; Петров П. А.; E. A. Filippova; Филиппова Е. А.; T. S. Sukhikh; Сухих Т. С.

doi:10.31857/S0132344X24100033

Adducts of Sterically Hindered Tellurium Catecholate with N-Methylpyrrolidone

作者: Petrov P.A.¹, Filippova E.A.¹, Sukhikh T.S.¹
隶属关系:
1. Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences
期: 卷 50, 编号 10 (2024)
页面: 661-668
栏目: Articles
URL: https://bakhtiniada.ru/0132-344X/article/view/273475
DOI: https://doi.org/10.31857/S0132344X24100033
EDN: https://elibrary.ru/LPWAYK
ID: 273475

如何引用文章

全文:

开放存取

##reader.subscriptionAccessGranted##
受限制的访问

订阅存取

详细
全文:
作者简介
参考
补充文件
统计

详细

The formation of adducts of tellurium(IV) 3,6-di-tert-butyl catecholate (Te(Cat³⁶)₂) with N-methylpyrrolidone (NMP) is studied. The crystallization from a CH₂Cl₂–NMP–aromatic hydrocarbon mixture is found to result in the formation of dimeric complexes [{Te(Cat³⁶)₂}₂(μ-NMP)(μ-arene)] (arene = C₆H₆, C₇H₈), whereas mononuclear [Te(Cat³⁶)₂(NMP)₂] is formed from a CH₂Cl₂–NMP–alkane mixture. The formation of the adducts with aromatic hydrocarbons indicates a possibility of using the tellurium complexes for the separation of hydrocarbon mixtures, including an industrially important benzene–cyclohexane mixture.

关键词

tellurium, quinones, XRD, N-methylpyrrolidone, NMR

全文:

参考

Poddel’sky A.I., Cherkasov V.K., Abakumov G.A. // Coord. Chem. Rev. 2009. V. 253. P. 291.
Kaim W. // Inorg. Chem. 2011. V. 50. P. 9752.
Abakumov G.A., Poddelsky A.I., Grunova E.V. et al. // Angew. Chem., Int. Ed. 2005. V. 44. P. 2767.
Cherkasov V.K., Abakumov G.A., Grunova E.V. et al. // Chem. Eur. J. 2006. V. 12. P. 3916.
Poddel’sky A.I., Kurskii Yu.A., Piskunov A.V. et al. // Appl. Organomet. Chem. 2011. V. 25. P. 180.
Ilyakina E.V., Poddel’sky A.I., Cherkasov V.K., Abakumov G.A. // Mendeleev Commun. 2012. V. 22. P. 208.
Lado A.V., Piskunov, A.V., Cherkasov, V.K. et al // Russ. J. Coord. Chem. 2006. V. 32. P. 173. doi: 10.1134/S1070328406030031
Piskunov A.V., Ershova I.V., Fukin G.K., Shavyrin A.S. // Inorg. Chem. Commun. 2013. V. 38. P. 127.
Piskunov A.V., Meshcheryakova I.N., Fukin G.K. et al. // Dalton Trans. 2013. V. 42. P. 10533.
Thorwart T., Hartman D., Greb L. // Chem. Eur. J. 2022. V. 23. Art. e202202273.
Thorwart T., Roth D., Greb L. // Chem. Eur. J. 2021. V. 21. P. 10422.
Hartmann D., Braner S., Greb L. // Chem. Commun. 2021. V. 57. P. 8572.
Ansmann N., Thorwart T., Greb L. // Angew. Chem. Int. Ed. 2022. V. 61. Art. e202210132.
Arsenyeva K.V., Pashanova K.I., Trofimova O.Yu. et al. // New J. Chem. 2021. V. 45. P. 11758.
Arsenyeva K.V., Klimashevskaya A.V., Pashanova, K.I. et al. // Appl. Organomet. Chem. 2022. V. 36. Art. e6593.
Maleeva A.V., Ershova I.V., Trofimova O.Y. et al. // Mendeleev Commun. 2022. V. 32. P. 83.
Klimashevskaya A.V., Arsenyeva K.V., Cherkasov A.V. et al. // J. Struct. Chem. 2023. V. 64. P. 2271. doi: 10.1134/S0022476623120016
Klimashevskaya A. V., Arsenyeva, K. V., Maleeva A. V. et al. // Eur. J. Inorg. Chem. 2023. Art. e202300540.
Nikolaevskaya E.N., Syroeshkin M.A., Egorov M.P. // Mendeleev Commun. 2023. V. 33. P. 733.
Ershova I.V., Piskunov A.V., Cherkasov V.K. // Russ. Chem. Rev. 2020. V. 89. P. 1157.
Chegerev M.G., Starikova A.A., Piskunov A.V., Cherkasov V.K. // Eur. J. Inorg. Chem. 2016. V. 2016. P. 252.
Chegerev M.G., Piskunov A.V., Starikova A.A. et al. // Eur. J. Inorg. Chem. 2018. V. 2018. P. 1087.
Greb L. // Eur. J. Inorg. Chem. 2022. V. 2022. Art. e202100871.
Antikainen P.J., Mälkönen P.J. // Z. Anorg. Allg. Chem. 1959. V. 299. P. 292.
Lindqvist O. // Acta Chem. Scand. 1967. V. 21. P. 1473.
Annan T.A., Ozarowski A., Tian Z., Tuck D.G. // Dalton Trans. 1992. P. 2931.
Kieser J.M., Jones L.O., Lin N.J. et al. // Inorg. Chem. 2021. V. 60. P. 3460.
Petrov P.A., Filippova E.A., Sukhikh T.S. et al. // Inorg. Chem. 2022. V. 61. P. 9184.
Petrov P.A. // Russ. J. Coord. Chem. 2023. V. 49. P. 357. doi: 10.1134/S1070328423600262
Petrov P.A., Kadilenko E.M., Sukhikh T.S. et al. // Chem. Eur. J. 2020. V. 26. P. 14688.
Mahmudov K.T., Kopylovich M.N., Guedes da Silva M.F.C., Pombeiro A.J.L. // Dalton Trans. 2017. V. 46. P. 10121.
Fourmigué M., Dhaka A. // Coord. Chem. Rev. 2020. V. 403. P. 213084.
Pale P., Mamane V. // Chem. Eur. J. 2023. V. 29. Art. e202302755.
Bruker Apex3 software suite: Apex3, SADABS-2016/2 and SAINT. Version 2018.7-2. Madison (WI, USA): Bruker AXS Inc., 2017.
Sheldrick G.M. // Acta Crystallogr. A. 2015. V. 71. P. 3.
Sheldrick G.M. // Acta Crystallogr. C. 2015. V. 71. P. 3.
Dolomanov O.V., Bourhis L.J., Gildea R.J. et al. // J. Appl. Cryst. 2009. V. 42. P. 339.
Scherpf T., Feichtner K.-S., Gessner V.H. // Angew. Chem. Int. Ed. 2017. V. 56. P. 3275.
Schmid R. // J. Solution Chem. 1983. V. 12. P. 135.
O’Quinn G.K., Rudd M.D., Kautz J.A. // Phosphorus, Sulfur, Silicon Relat. Elem. 2002. V. 177. P. 853.
Fulmer G.R., Miller A.J., Sherden N.H. et al. // Organometallics. 2020. V. 29. P. 2176.