Chemical Equilibrium and the Kinetics of Transesterification Reactions of Fluoroorganic Esters and Acids

S. Ya. Kvashnin; E. V. Lupachev; V. A. Lotkhov; N. N. Kuritsyn; N. N. Kulov

doi:10.1134/S0040579517060100

Chemical Equilibrium and the Kinetics of Transesterification Reactions of Fluoroorganic Esters and Acids

Авторы: Kvashnin S.Y.¹, Lupachev E.V.¹, Lotkhov V.A.¹, Kuritsyn N.N.¹, Kulov N.N.¹
Учреждения:
1. Kurnakov Institute of General and Inorganic Chemistry
Выпуск: Том 51, № 6 (2017)
Страницы: 1012-1020
Раздел: Article
URL: https://bakhtiniada.ru/0040-5795/article/view/171840
DOI: https://doi.org/10.1134/S0040579517060100
ID: 171840

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Аннотация

An experimental study has been carried out of the chemical equilibrium and chemical kinetics of the reactions of transesterification of fluoroorganic esters for two systems under static conditions. The experiments were carried out at both the boiling point of the mixture and at constant temperature. For the transesterification reaction of methyl ester of bromodifluoroacetic acid with trifluoroacetic acid, the dependence of the reaction rate on temperature has been determined.