Identification of B−H···H−C Specific Interactions Observed in Complexes [M(solv) 6 ][B 10 H 10 ] (M = Co, Ni) by Spectral Analytical Methods

L. V. Goeva; V. V. Avdeeva; E. A. Malinina; N. T. Kuznetsov

doi:10.1134/S0036023618080089

Identification of B−H···H−C Specific Interactions Observed in Complexes [M(solv)₆][B₁₀H₁₀] (M = Co, Ni) by Spectral Analytical Methods

作者: Goeva L.V.¹, Avdeeva V.V.¹, Malinina E.A.¹, Kuznetsov N.T.¹
隶属关系:
1. Kurnakov Institute of General and Inorganic Chemistry
期: 卷 63, 编号 8 (2018)
页面: 1050-1055
栏目: Coordination Compounds
URL: https://bakhtiniada.ru/0036-0236/article/view/168902
DOI: https://doi.org/10.1134/S0036023618080089
ID: 168902

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The B−H···H−C specific interactions observed in complexes [M(solv)₆][B₁₀H₁₀], where M= Co(II), Ni(II); solv = DMF or DMSO, are analyzed based on the correlation between the X-ray diffraction data and the results of IR and UV spectroscopic studies. Comparing the experimental data obtained earlier with those reported here allows us to elucidate one of the reasons that do not permit unambiguously determine the presence of long-range contacts when interpreting spectral data.