电邮这篇文章 The Insertion of Carbon Dioxide in Combination with RNCS (R Is Et, Ph) or N,N′-Dihexylcarbodiimide into the Re–O(R) Bonds
- 作者: Ovchinnikova N.A.1, Drobot D.V.2, Eremenko I.L.1, Mulyukina V.A.3, Parshakov A.S.1, Minaeva N.A.1, Aleksandrov G.G.1, Kirakosyan G.A.1, Yakushev I.A.1, Mikhailov Y.N.1, Surazhskaya M.D.1, Ellert O.G.1, Minin V.V.1, Efimov N.N.1, Kulikova E.S.2
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隶属关系:
- Kurnakov Institute of General and Inorganic Chemistry
- Moscow Technological University
- AO NPP Research and Production Corporation “Toriy”
- 期: 卷 63, 编号 2 (2018)
- 页面: 191-196
- 栏目: Coordination Compounds
- URL: https://bakhtiniada.ru/0036-0236/article/view/168408
- DOI: https://doi.org/10.1134/S003602361802016X
- ID: 168408
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The heteromolecular insertion of carbon dioxide in combination with heterocumulenes, iso(thio)cyanates or N,N′-dicyclohexylcarbodiimide, into rhenium–alkoxy group bond was accomplished for the first time in relation to reactivity of rhenium oxoalkoxides. The ease of combined insertion of iso(thio)cyanate and carbon dioxide into Re–O(Me) bond is determined by the nature of the heterocumulene organic group. Indeed, if ethyl iso(thio)cyanate is used in the reaction, the insertion is reversible, whereas the reaction with PhNCS (unlike PhNCO) together with carbon dioxide leads to complete insertion into two Re–O(R) bonds to give the insertion product (OMe)10O6Re4[OC(O){N(Ph)C(S)}2-OMe]2. In similar reactions carried out with N,N′-dicyclohexylcarbodiimide, a dependence of the number of bonds participating in the inner-sphere condensation of the inserted moieties on the duration of the experiment was found for the first time. An increase in the time of synthesis from 3 to 5 h results in insertion involving six rather than three bonds, the heteromolecular insertion products being (OMe),O6Re4{OC(O)[(Hex)N=C=N(Hex)]2}3 and (OMe)6O6Re4{OC(O)[(Hex)N=C=N(Hex)]2}6, respectively.
作者简介
N. Ovchinnikova
Kurnakov Institute of General and Inorganic Chemistry
编辑信件的主要联系方式.
Email: talan44@mail.ru
俄罗斯联邦, Moscow, 119991
D. Drobot
Moscow Technological University
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俄罗斯联邦, Moscow, 119571
I. Eremenko
Kurnakov Institute of General and Inorganic Chemistry
Email: talan44@mail.ru
俄罗斯联邦, Moscow, 119991
V. Mulyukina
AO NPP Research and Production Corporation “Toriy”
Email: talan44@mail.ru
俄罗斯联邦, Moscow, 117342
A. Parshakov
Kurnakov Institute of General and Inorganic Chemistry
Email: talan44@mail.ru
俄罗斯联邦, Moscow, 119991
N. Minaeva
Kurnakov Institute of General and Inorganic Chemistry
Email: talan44@mail.ru
俄罗斯联邦, Moscow, 119991
G. Aleksandrov
Kurnakov Institute of General and Inorganic Chemistry
Email: talan44@mail.ru
俄罗斯联邦, Moscow, 119991
G. Kirakosyan
Kurnakov Institute of General and Inorganic Chemistry
Email: talan44@mail.ru
俄罗斯联邦, Moscow, 119991
I. Yakushev
Kurnakov Institute of General and Inorganic Chemistry
Email: talan44@mail.ru
俄罗斯联邦, Moscow, 119991
Yu. Mikhailov
Kurnakov Institute of General and Inorganic Chemistry
Email: talan44@mail.ru
俄罗斯联邦, Moscow, 119991
M. Surazhskaya
Kurnakov Institute of General and Inorganic Chemistry
Email: talan44@mail.ru
俄罗斯联邦, Moscow, 119991
O. Ellert
Kurnakov Institute of General and Inorganic Chemistry
Email: talan44@mail.ru
俄罗斯联邦, Moscow, 119991
V. Minin
Kurnakov Institute of General and Inorganic Chemistry
Email: talan44@mail.ru
俄罗斯联邦, Moscow, 119991
N. Efimov
Kurnakov Institute of General and Inorganic Chemistry
Email: talan44@mail.ru
俄罗斯联邦, Moscow, 119991
E. Kulikova
Moscow Technological University
Email: talan44@mail.ru
俄罗斯联邦, Moscow, 119571
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