Tetra- and triarylantimony pentafluoroand pentachlorophenoxides: Synthesis and structure

详细

2,3,4,5,6-Pentafluorophenoxytetraphenylantimony (I), 2,3,4,5,6-pentachlorophenoxytetraphenylantimony (_II), 2,3,4,5,6-pentafluorophenoxytetra-p-tolylantimony (III), and 2,3,4,5,6-pentachlorophenoxytetra-p-tolylantimony (IV) were synthesized by the reaction of pentaarylantimony (Ar = Ph, p-Tol) with pentafluoro- and pentachlorophenol in toluene. Compounds I–IV were also synthesized with yields of up to 95% from pentaarylantimony and triarylantimony diaroxides. Triarylantimony diaroxides Ph₃Sb(OC₆F₅)₂ (V), Ph₃Sb(OC₆Cl₅)₂ (VI), p-Tol₃Sb(OC₆F₅)₂ (VII), p-Tol₃Sb(OC₆Cl₅)₂ (VIII) were synthesized from triarylantimony, tert-butylhydroperoxide, and phenol in ether. The Sb atoms in compounds I–VIII had a distorted trigonal bipyramidal coordination with electronegative ligands in axial positions.