Synthesis, Crystal Structure, and Molecular Structure of Maleate Tris(Benzohydrazide) Cobalt(II) Tetrahydrate [Co(L1)3](Mal) · 4H2O and Maleate Tris(Phenylacethydrazide) Nikel(II) Monohydrate [Ni(L2)3](Mal) · H2O
- Авторы: Sergienko V.S.1,2, Koksharova T.V.3, Surazhskaya M.D.1, Mandzii T.V.3, Churakov A.V.1
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Учреждения:
- Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
- All-Russian Institute for Scientific and Technical Information, Russian Academy of Sciences
- Odessa National University
- Выпуск: Том 64, № 11 (2019)
- Страницы: 1396-1404
- Раздел: Coordination Compounds
- URL: https://bakhtiniada.ru/0036-0236/article/view/169548
- DOI: https://doi.org/10.1134/S0036023619110172
- ID: 169548
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Аннотация
Coordination compounds [Co(L1)3](Mal) · 4H2O (I) and [Ni(L2)3](Mal) · H2O (II) (L1 is benzohydrazide, L2 is phenylacethydrazide, and H2Mal is maleic acid) have been synthesized and characterized by IR spectroscopy and diffuse reflectance spectroscopy. Crystal structures of I and II have been determined by single-crystal X-ray diffraction. Structural units of crystals I and II are complex cations [Co(L1)3]2+ and [Ni(L2)3]2+, respectively, maleate-ions Mal2–, and crystallized water molecules bound by a branched system of hydrogen bonds. Metal atoms at the complex cations of crystals I and II have octahedral coordination (3O + 3N) formed by three bidentate chelate ligands Ln (n = 1, 2).
Об авторах
V. Sergienko
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences; All-Russian Institute for Scientific and Technical Information, Russian Academy of Sciences
Автор, ответственный за переписку.
Email: sergienko@igic.ras.ru
Россия, Moscow, 119991; Moscow, 125190
T. Koksharova
Odessa National University
Email: sergienko@igic.ras.ru
Украина, Odessa, 65082
M. Surazhskaya
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: sergienko@igic.ras.ru
Россия, Moscow, 119991
T. Mandzii
Odessa National University
Email: sergienko@igic.ras.ru
Украина, Odessa, 65082
A. Churakov
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: sergienko@igic.ras.ru
Россия, Moscow, 119991
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