Enviar artigo por via de e-mail Nucleophilic Addition Reaction of Secondary Amines to Acetonitrilium closo-Decaborate [2-B10H9NCCH3]–
- Autores: Zhdanov A.P.1, Nelyubin A.V.1, Klyukin I.N.1, Selivanov N.A.1, Bortnikov E.O.1,2, Grigoriev M.S.3, Zhizhin K.Y.1, Kuznetsov N.T.1
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Afiliações:
- Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
- Mendeleev University of Chemical Technology, HCC Russian Academy of Sciences
- Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences
- Edição: Volume 64, Nº 7 (2019)
- Páginas: 841-846
- Seção: Synthesis and Properties of Inorganic Compounds
- URL: https://bakhtiniada.ru/0036-0236/article/view/169405
- DOI: https://doi.org/10.1134/S0036023619070180
- ID: 169405
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Resumo
The work is devoted to the study of the process of nucleophilic addition of secondary amines to a multiple bond of the nitrile derivative of the closo-decaborate anion (NBu4) [2-B10H9NCCH3]. The process results to the regioselective and stereoselective formation of disubstituted amidines. The process is carried out under mild conditions and allows functionalization of amines of various structure. The compounds obtained are characterized by multinuclear NMR spectroscopy, IR spectroscopy, elemental analysis. For the substances (NBu4)[2-B10H9(E-NH=C(N(CH2)5CH3)] and (NBu4)[2-B10H9(E-NH=C(N(C2H4)2O)] the structures were confirmed by X-ray diffraction.
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Sobre autores
A. Zhdanov
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Autor responsável pela correspondência
Email: zhdanov@igic.ras.ru
Rússia, Moscow, 119991
A. Nelyubin
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Email: zhdanov@igic.ras.ru
Rússia, Moscow, 119991
I. Klyukin
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Email: zhdanov@igic.ras.ru
Rússia, Moscow, 119991
N. Selivanov
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Email: zhdanov@igic.ras.ru
Rússia, Moscow, 119991
E. Bortnikov
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences; Mendeleev University of Chemical Technology, HCC Russian Academy of Sciences
Email: zhdanov@igic.ras.ru
Rússia, Moscow, 119991; Moscow, 125047
M. Grigoriev
Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences
Email: zhdanov@igic.ras.ru
Rússia, Moscow, 119071
K. Zhizhin
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Email: zhdanov@igic.ras.ru
Rússia, Moscow, 119991
N. Kuznetsov
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Email: zhdanov@igic.ras.ru
Rússia, Moscow, 119991
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