Отправить статью по E-mail Extraction of Rare Earth Elements(III) with Picrolonic Acid Mixtures with Phosphoryl-Substituted Aza Podands
- Авторы: Turanov A.N.1, Karandashev V.K.2,3, Kharlamov A.V.4, Bondarenko N.A.4
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Учреждения:
- Institute of Solid-State Physics
- Institute of Microelectronics Technology and High Purity Materials
- National University of Science and Technology “MISIS”
- Institute of Chemical Reagents and High Purity Chemical Substances
- Выпуск: Том 63, № 12 (2018)
- Страницы: 1673-1678
- Раздел: Physical Chemistry of Solutions
- URL: https://bakhtiniada.ru/0036-0236/article/view/169168
- DOI: https://doi.org/10.1134/S0036023618120203
- ID: 169168
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Аннотация
Extraction of rare earth element(III) (REE) ions from chloride solutions with picrolonic acid mixtures with phosphoryl-substituted aza podands in chloroform has been studied. A considerable synergetic effect observed has been caused by the formation of hydrophobic mixed-ligand complexes of REE. The stoichiometry of extracted complexes has been determined and extraction constants have been calculated. The effect of aqueous phase composition, organic solvent nature, and the structure of phosphoryl-substituted aza podands on the efficiency of REE(III) recovery into organic phase have been considered.
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A. Turanov
Institute of Solid-State Physics
Автор, ответственный за переписку.
Email: turanov@issp.ac.ru
Россия, Chernogolovka, Moscow oblast, 142432
V. Karandashev
Institute of Microelectronics Technology and High Purity Materials; National University of Science and Technology “MISIS”
Email: turanov@issp.ac.ru
Россия, Chernogolovka, Moscow oblast, 142432; Moscow, 119991
A. Kharlamov
Institute of Chemical Reagents and High Purity Chemical Substances
Email: turanov@issp.ac.ru
Россия, Moscow, 107076
N. Bondarenko
Institute of Chemical Reagents and High Purity Chemical Substances
Email: turanov@issp.ac.ru
Россия, Moscow, 107076
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