New Solvate Polymorphs of Lanthanide Trisacetylacetonates: Crystal Structures of [Ln(acac)3(H2O)2] · Solv (Ln = Eu, Dy; Solv = Thf, H2O + EtOH, MeOH)
- Авторы: Ilyukhin A.B.1, Gavrikov A.V.1, Dobrokhotova Z.V.1, Novotortsev V.M.1
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Учреждения:
- Kurnakov Institute of General and Inorganic Chemistry
- Выпуск: Том 63, № 9 (2018)
- Страницы: 1186-1191
- Раздел: Coordination Compounds
- URL: https://bakhtiniada.ru/0036-0236/article/view/168976
- DOI: https://doi.org/10.1134/S003602361809005X
- ID: 168976
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Аннотация
Solvate polymorphs of [Dy(acac)3(H2O)2] · Thf, [Ln(acac)3(H2O)2] · H2O · EtOH (Ln = Eu, Dy) and [Dy(acac)3(H2O)2] · 1.5MeOH, which belongs to a new structural type, are isolated as single crystals. The structures of the prepared compounds are determined by X-ray crystallography, and the effect of solvate molecules on their crystal structures is discussed.
Об авторах
A. Ilyukhin
Kurnakov Institute of General and Inorganic Chemistry
Автор, ответственный за переписку.
Email: ilyukhin@gmail.com
Россия, Moscow, 119991
A. Gavrikov
Kurnakov Institute of General and Inorganic Chemistry
Email: ilyukhin@gmail.com
Россия, Moscow, 119991
Zh. Dobrokhotova
Kurnakov Institute of General and Inorganic Chemistry
Email: ilyukhin@gmail.com
Россия, Moscow, 119991
V. Novotortsev
Kurnakov Institute of General and Inorganic Chemistry
Email: ilyukhin@gmail.com
Россия, Moscow, 119991
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