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Thermal Decomposition of Unsaturated Nickel(II) Dicarboxylates


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Resumo

Thermal decomposition of nickel hydrogen carboxylates (NHCs) of unsaturated dicarboxylic acids has been studied by the TGA/DTA method in combination with DSC analysis and mass spectrometry of gaseous thermolysis products. The temperature ranges of the key stages of the thermal decomposition of NHCs were determined: (1) dehydration, 50–275°C; (2) polymerization of dehydrated carboxylate, 125–360°C; (3) decarboxylation, 290–450°C. A conclusion has been made that these stages can overlap one another and proceed simultaneously.

Sobre autores

V. Musatova

MIREA–Russian Technological University (Lomonosov Institute of Fine Chemical Technologies)

Email: srg.semenov@gmail.com
Rússia, Moscow, 119454

D. Drobot

MIREA–Russian Technological University (Lomonosov Institute of Fine Chemical Technologies)

Email: srg.semenov@gmail.com
Rússia, Moscow, 119454

G. Dzhardimalieva

Institute of Problems of Chemical Physics

Email: srg.semenov@gmail.com
Rússia, Chernogolovka, Moscow oblast, 142432

S. Semenov

MIREA–Russian Technological University (Lomonosov Institute of Fine Chemical Technologies)

Autor responsável pela correspondência
Email: srg.semenov@gmail.com
Rússia, Moscow, 119454

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