Email this article Effects of the Nature of Transition Metal on the Composition and Structure of Reaction Products of M[(OOCC5H4)Mn(CO)3]2[O(H)Me]4 (М = Cu(II), Ni(II), Co(II), or Mn(II)) with 1,10-Phenanthroline
- Authors: Grineva A.A.1, Uvarova M.A.1, Datchuk R.R.1, Nefedov S.E.1
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Affiliations:
- Kurnakov Institute of General and Inorganic Chemistry
- Issue: Vol 63, No 5 (2018)
- Pages: 610-617
- Section: Coordination Compounds
- URL: https://bakhtiniada.ru/0036-0236/article/view/168661
- DOI: https://doi.org/10.1134/S0036023618050091
- ID: 168661
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Abstract
Reactions of M[(OOCC5H4)Mn(CO)3]2[O(H)Me]4 (M = Ni(II), Co(II), or Mn(II)) adducts with 1,10-phenanthroline in chloroform at room temperature are found to yield complexes PhennM[(OOCC5H4) Mn(CO)3]2 (Co(II) or Mn(II), n = 2; M = Ni(II), n = 3). A similar reaction of dimeric Cu2[μ-(OOCC5H4) Mn(CO)3]4[O(H)Me]2 yields mononuclear PhenCu[(OOCC5H4)Mn(CO)3][O(H)Me] · MeOH. The resulting complexes are isolated in high yields and characterized by chemical analysis, IR spectroscopy, and X-ray crystallography.
About the authors
A. A. Grineva
Kurnakov Institute of General and Inorganic Chemistry
Email: snef@igic.ras.ru
Russian Federation, Moscow, 119991
M. A. Uvarova
Kurnakov Institute of General and Inorganic Chemistry
Email: snef@igic.ras.ru
Russian Federation, Moscow, 119991
R. R. Datchuk
Kurnakov Institute of General and Inorganic Chemistry
Email: snef@igic.ras.ru
Russian Federation, Moscow, 119991
S. E. Nefedov
Kurnakov Institute of General and Inorganic Chemistry
Author for correspondence.
Email: snef@igic.ras.ru
Russian Federation, Moscow, 119991
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