Email this article Sulfated alumina aerogel-based superacid catalysts for 1-hexene oligomerization
- Authors: Lermontov S.A.1, Yurkova L.L.1, Straumal E.A.1, Baranchikov A.E.2, Shunina I.G.3, Ivanov V.K.2
-
Affiliations:
- Institute of Physiologically Active Compounds
- Kurnakov Institute of General and Inorganic Chemistry
- Institute of Problems of Chemical Physics
- Issue: Vol 61, No 1 (2016)
- Pages: 7-10
- Section: Synthesis and Properties of Inorganic Compounds
- URL: https://bakhtiniada.ru/0036-0236/article/view/167025
- DOI: https://doi.org/10.1134/S0036023616010137
- ID: 167025
Cite item
Open Access
Access granted
Subscription Access
Abstract
Al2O3 aerogel samples were synthesized by supercritical drying in two different media: isopropanol and methyl tert-butyl ether. After sulfation in a SO2Cl2 vapor, the aerogel acquired superacid properties (–12.4 ≤ H0 ≤–11.99) and efficiently catalyzed 1-hexene oligomerization and dimerization.
Keywords
About the authors
S. A. Lermontov
Institute of Physiologically Active Compounds
Author for correspondence.
Email: lermontov52@yandex.ru
Russian Federation, Severnyi proezd 1, Chernogolovka, Moscow oblast, 142432
L. L. Yurkova
Institute of Physiologically Active Compounds
Email: lermontov52@yandex.ru
Russian Federation, Severnyi proezd 1, Chernogolovka, Moscow oblast, 142432
E. A. Straumal
Institute of Physiologically Active Compounds
Email: lermontov52@yandex.ru
Russian Federation, Severnyi proezd 1, Chernogolovka, Moscow oblast, 142432
A. E. Baranchikov
Kurnakov Institute of General and Inorganic Chemistry
Email: lermontov52@yandex.ru
Russian Federation, Leninskii pr. 31, Moscow, 119991
I. G. Shunina
Institute of Problems of Chemical Physics
Email: lermontov52@yandex.ru
Russian Federation, Moscow oblast, 142432
V. K. Ivanov
Kurnakov Institute of General and Inorganic Chemistry
Email: lermontov52@yandex.ru
Russian Federation, Leninskii pr. 31, Moscow, 119991
Supplementary files
