Email this article Crystal structure of [Bi(N-ethylthiourea)4(ClO4)2]ClO4
- Authors: Vasil’ev A.D.1,2, Golovnev N.N.2, Lesnikov M.K.2
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Affiliations:
- Kirensky Institute of Physics
- Siberian Federal University
- Issue: Vol 61, No 6 (2016)
- Pages: 704-707
- Section: Coordination Compounds
- URL: https://bakhtiniada.ru/0036-0236/article/view/166504
- DOI: https://doi.org/10.1134/S003602361606022X
- ID: 166504
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Abstract
The structure of the bismuth(III) complex with N-ethylthiourea (Ettu) has been determined for the first time. We found that the crystal structure of [Bi(Ettu)4(ClO4)2]ClO4 is built of distorted octahedral cations [Bi(Ettu–S)4(ClO4)2]ClO4]+ and anions ClO4-. The deviation of one of the two independent Ettu molecules from the plane structure is explained by the mutual repulsion of the ligands and the formation features of hydrogen bonds. The C2H5(Ettu) group is in the cis position relative to the thiocarbonyl group.
About the authors
A. D. Vasil’ev
Kirensky Institute of Physics; Siberian Federal University
Email: ngolovnev@sfu-kras.ru
Russian Federation, Krasnoyarsk; Krasnoyarsk
N. N. Golovnev
Siberian Federal University
Author for correspondence.
Email: ngolovnev@sfu-kras.ru
Russian Federation, Krasnoyarsk
M. K. Lesnikov
Siberian Federal University
Email: ngolovnev@sfu-kras.ru
Russian Federation, Krasnoyarsk
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