Russian Journal of Inorganic Chemistry, Vol 63, No 3 (2018)

Study of the Structure of Lithium Thiocyanate Complexes with Benzo-15-Crown-5 by X-ray Diffraction and IR Spectroscopy

Kuz’mina L.G., Demina L.I., Demin S.V., Shokurova N.A., Zhilov V.I., Tsivadze A.Y.

Abstract


The complex formation of lithium thiocyanate with benzo-15-crown-5 (B15C5) was studied. The possibility of formation of both anhydrous and crystal water-containing complexes was demonstrated. The complexes LiB15C5NCS and LiB15C5H2ONCS were synthesized and characterized by X-ray diffraction and IR spectroscopy.