Synthesis, Molecular and Crystal Structure of Ethyl 5-Cyano-2-(Dicyanomethyl)-2-Methyl-4-Oxo-6-Phenyl-3-Azabicyclo[3.1.0]Hexane-1-Carboxylate

A. I. Ismiyev; K. A. Potekhin; A. V. Maleev; R. K. Askerov; A. M. Maharramov

doi:10.1134/S0022476619030181

Synthesis, Molecular and Crystal Structure of Ethyl 5-Cyano-2-(Dicyanomethyl)-2-Methyl-4-Oxo-6-Phenyl-3-Azabicyclo[3.1.0]Hexane-1-Carboxylate

作者: Ismiyev A.I.¹, Potekhin K.A.², Maleev A.V.², Askerov R.K.¹, Maharramov A.M.¹
隶属关系:
1. Baku State University
2. Vladimir State University
期: 卷 60, 编号 3 (2019)
页面: 485-493
栏目: Article
URL: https://bakhtiniada.ru/0022-4766/article/view/162083
DOI: https://doi.org/10.1134/S0022476619030181
ID: 162083

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详细

As a result of triple condensation of malonodinitrile with benzaldehyde and ethyl 2-chloro-3-oxobutanoate a compound with 3-azabicyclo[3.1.0]hexane framework is formed whose crystal structure is determined by X-ray crystallography. In the crystal structure a layered character of the molecular packing is found. Molecules are linked in the layer by H bonds of N-H…O=C and C-H…O=C types and also a large number of atom-atom contacts whose energy corresponds to potential wells.