Crystal structure of two homochiral metal-organic polymers based on  S -3,3-dimethyllactic acid

M. S. Zavakhina; D. G. Samsonenko; V. P. Fedin

doi:10.1134/S0022476616040326

Crystal structure of two homochiral metal-organic polymers based on S-3,3-dimethyllactic acid

作者: Zavakhina M.S.¹, Samsonenko D.G.¹, Fedin V.P.¹
隶属关系:
1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch
期: 卷 57, 编号 4 (2016)
页面: 830-834
栏目: Brief Communications
URL: https://bakhtiniada.ru/0022-4766/article/view/160105
DOI: https://doi.org/10.1134/S0022476616040326
ID: 160105

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详细

By heating of an aqueous solution of zinc(II) or cobalt(II) acetates, 4,4-bipyridyl (bpy), and S-3,3-dimethyl hydroxypropionic acid (H₂dml) two homochiral coordination polymers [Zn(H₂O)(bpy)(Hdml)](CH₃COO)∙ ∙2H₂O (1) and [Co(H₂O)(bpy)(Hdml)₂] (2) are obtained. The crystal structure is determined by single crystal X-ray diffraction. Compound 1 has a layered structure and compound 2 has a chain structure.