Отправить статью по E-mail Perfluorobenzocyclobutene Radical Anion: A Structurally Flexible Particle
- Авторы: Beregovaya I.V.1, Shchegoleva L.N.1, Borovkov V.I.2, Karpov V.M.1
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Учреждения:
- Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch
- Voevodsky Institute of Chemical Kinetics and Combustion, Siberian Branch
- Выпуск: Том 60, № 3 (2019)
- Страницы: 373-376
- Раздел: Article
- URL: https://bakhtiniada.ru/0022-4766/article/view/162069
- DOI: https://doi.org/10.1134/S0022476619030041
- ID: 162069
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Аннотация
The method of time resolved magnetic field effects in the recombination fluorescence of spin-correlated radical ion pairs is used to detect for the first time the perfluorobenzocyclobutene radical anion. The quantum chemical analysis of the potential energy surface testifies that the particle is structurally flexible with respect to the pseudo-rotation coordinate. The calculated values of hyperfine interaction constants averaged over global minima are close to those estimated from the experimental data of time resolved magnetic field effects.
Об авторах
I. Beregovaya
Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch
Автор, ответственный за переписку.
Email: ivb@nioch.nsc.ru
Россия, Novosibirsk
L. Shchegoleva
Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch
Email: ivb@nioch.nsc.ru
Россия, Novosibirsk
V. Borovkov
Voevodsky Institute of Chemical Kinetics and Combustion, Siberian Branch
Email: ivb@nioch.nsc.ru
Россия, Novosibirsk
V. Karpov
Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch
Email: ivb@nioch.nsc.ru
Россия, Novosibirsk
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