Отправить статью по E-mail Structural Packing Features of [ML2](ReO4)2 (M = Cu, Ni; L = 5,5,7,12,12,14-Hexamethyl-1,4,8,11-Tetraaza-Cyclotetradecane)
- Авторы: Bykova E.A.1, Khranenko S.P.2, Gromilov S.A.2,3
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Учреждения:
- Bayerisches Geoinstitut
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch
- Novosibirsk State University
- Выпуск: Том 59, № 1 (2018)
- Страницы: 172-176
- Раздел: Article
- URL: https://bakhtiniada.ru/0022-4766/article/view/161852
- DOI: https://doi.org/10.1134/S0022476618010262
- ID: 161852
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Аннотация
The crystal structures of [CuL2](ReO4)2 and [NiL2](ReO4)2 (L = 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraaza-cyclotetradecane) are studied. The crystal structural data for [CuL2](ReO4)2, C16H32CuN4O8Re2: a = 13.5523(7) Å, b = 9.3446(4) Å, c = 18.4410(9) Å, V = 2335.38(19) Å3, space group Pbca, Z = 4, dx = 2.402 g/cm3; the copper atom coordination C–N of (2×)1.973(5) Å and (2×)2.008(5) Å, the additional coordination Cu…O of (2×)2.642 Å. The crystal structural data for [NiL2](ReO4)2, C16H32NiN4O8Re2: a = 8.9308(2) Å, b = 14.3479(3) Å, c = 18.6501(4) Å, β = 91.492(1)°, V = 2388.98(9) Å3, space group P21/c, Z = 4, dx = 2.334 g/cm3; the nickel atom coordination Ni–N of 1.889(4)-1.917(3) Å, the additional coordination Ni…O of 2.750(3) Å.
Об авторах
E. Bykova
Bayerisches Geoinstitut
Email: grom@niic.nsc.ru
Германия, Bayreuth
S. Khranenko
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Email: grom@niic.nsc.ru
Россия, Novosibirsk
S. Gromilov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk State University
Автор, ответственный за переписку.
Email: grom@niic.nsc.ru
Россия, Novosibirsk; Novosibirsk
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