Отправить статью по E-mail Crystal structure and EPR spectra of (Bu4N)2[V(dmit)3]
- Авторы: Fomenko Y.S.1, Gushchin A.L.1,2, Nadolinny V.A.1, Abramov P.A.1, Sokolov M.N.1,2
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Учреждения:
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch
- Novosibirsk National Research State University
- Выпуск: Том 58, № 5 (2017)
- Страницы: 964-969
- Раздел: Article
- URL: https://bakhtiniada.ru/0022-4766/article/view/161503
- DOI: https://doi.org/10.1134/S0022476617050158
- ID: 161503
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Аннотация
The tris-chelate complex of vanadium(IV) (Bu4N)2[V(dmit)3] is prepared from VCl3 and (Bu4N)2[Zn(dmit)2] (dmit = isotrithionedithiolate C3S52–) and characterized by single crystal XRD and mass spectrometry. The complex crystallizes in the space group Pna21 and has a distorted octahedral environment of vanadium. The complex is paramagnetic and gives a characteristic EPR spectrum in both solution and solid phase. The g factors and hyperfine interaction constants are determined.
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Об авторах
Ya. Fomenko
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Email: gushchin@niic.nsc.ru
Россия, Novosibirsk
A. Gushchin
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk National Research State University
Автор, ответственный за переписку.
Email: gushchin@niic.nsc.ru
Россия, Novosibirsk; Novosibirsk
V. Nadolinny
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Email: gushchin@niic.nsc.ru
Россия, Novosibirsk
P. Abramov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Email: gushchin@niic.nsc.ru
Россия, Novosibirsk
M. Sokolov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk National Research State University
Email: gushchin@niic.nsc.ru
Россия, Novosibirsk; Novosibirsk
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