Molecular and crystal structure of a mixed-ligand cadmium complex with p-hydroxybenzoic acid and monoethanolamine
- Авторы: Ibragimov A.B.1, Ashurov Z.M.2, Zakirov B.S.1
-
Учреждения:
- Institute of General and Inorganic Chemistry
- Institute of Biorganic Chemistry
- Выпуск: Том 58, № 3 (2017)
- Страницы: 588-590
- Раздел: Brief Communications
- URL: https://bakhtiniada.ru/0022-4766/article/view/161312
- DOI: https://doi.org/10.1134/S0022476617030209
- ID: 161312
Цитировать
Аннотация
Single crystals of a mixed-ligand cadmium complex of the composition Cd(PHBA)2(MEA) 2 are grown from the solution of Cd(CH3OO)2, p-hydroxybenzoic acid (PHBA) and monoethanolamine (MEA) in aqueous ethanol. The crystallographic data are as follows: a = 11.6400(2) Å, b = 10.1363(1) Å, c = 16.6296(2) Å, β = 93.937(1)°, space group I2/a, V = 1957.44(5) Å3, Z = 4. In the complex molecule located on the twofold axis, ligands of both types are bidentately bound to the cadmium ion having the coordination number 8. In the crystal structure, two H bonds of the O–H•••O type combine complex molecules into layers parallel to the ab plane.
Ключевые слова
Об авторах
A. Ibragimov
Institute of General and Inorganic Chemistry
Автор, ответственный за переписку.
Email: aziz_ibragimov@mail.ru
Узбекистан, Tashkent
Zh. Ashurov
Institute of Biorganic Chemistry
Email: aziz_ibragimov@mail.ru
Узбекистан, Tashkent
B. Zakirov
Institute of General and Inorganic Chemistry
Email: aziz_ibragimov@mail.ru
Узбекистан, Tashkent
Дополнительные файлы
