New data on the structure of α-trans-[Pd(NH3)2Cl2]
- Авторы: Naumov D.Y.1, Khranenko S.P.1, Kuratieva N.V.1,2, Panchenko A.V.1,2, Gromilov S.A.1,2
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Учреждения:
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch
- Novosibirsk National Research State University
- Выпуск: Том 57, № 8 (2016)
- Страницы: 1600-1605
- Раздел: Article
- URL: https://bakhtiniada.ru/0022-4766/article/view/160428
- DOI: https://doi.org/10.1134/S0022476616080163
- ID: 160428
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Аннотация
Single crystal X-ray diffraction was applied for re-determination of the crystal structure of α-trans-[Pd(NH3)2Cl2]. It has been demonstrated that, in contrast to the literature data, the structure is disordered. This model does not require excess over-stoichiometric palladium. Two crystals obtained in the same experiment illustrate possible variations in the packing of the molecules of the complex.
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Об авторах
D. Naumov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Email: grom@niic.nsc.ru
Россия, Novosibirsk
S. Khranenko
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Email: grom@niic.nsc.ru
Россия, Novosibirsk
N. Kuratieva
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk National Research State University
Email: grom@niic.nsc.ru
Россия, Novosibirsk; Novosibirsk
A. Panchenko
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk National Research State University
Email: grom@niic.nsc.ru
Россия, Novosibirsk; Novosibirsk
S. Gromilov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk National Research State University
Автор, ответственный за переписку.
Email: grom@niic.nsc.ru
Россия, Novosibirsk; Novosibirsk
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