Crystal structure of a dinuclear nitrido-bridged ruthenium complex with pyridine ligands

Q. W. Chang; C. X. Yan; J. Jiang; Q. S. Ye; J. Yu; J. L. Chen; H. Cui; W. P. Liu

doi:10.1134/S0022476617030295

Crystal structure of a dinuclear nitrido-bridged ruthenium complex with pyridine ligands

Autores: Chang Q.W.¹, Yan C.X.¹, Jiang J.¹, Ye Q.S.¹, Yu J.¹, Chen J.L.¹, Cui H.¹, Liu W.P.¹
Afiliações:
1. State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals
Edição: Volume 58, Nº 3 (2017)
Páginas: 624-626
Seção: Brief Communications
URL: https://bakhtiniada.ru/0022-4766/article/view/161345
DOI: https://doi.org/10.1134/S0022476617030295
ID: 161345

Citar

Texto integral

Acesso aberto
Acesso é fechado

Acesso está concedido
Acesso é fechado

Somente assinantes

Resumo
Sobre autores
Bibliografia
Arquivos suplementares
Estatísticas

Resumo

A new dinuclear nitrido-bridged ruthenium complex with pyridine ligands ([PyH][Ru₂N(Py)₄Cl₆] (1) is synthesized by reacting K₃[Ru₂NCl₈(H₂O)2] (2) and excessive pyridine, then crystallized from dilute hydrochloric acid. Its crystal structure is determined by single crystal X-ray diffraction. The complex crystallizes in the form of red block crystals of the monoclinic symmetry and the space group C₂. The nitrido-bridged ruthenium complex has very short Ru–N distances.