Synthesis and Structural Characterization of Two Novel Copper(II) Schiff Base Complexes and their Water-Containing Supramolecular Structures


Дәйексөз келтіру

Толық мәтін

Ашық рұқсат Ашық рұқсат
Рұқсат жабық Рұқсат берілді
Рұқсат жабық Тек жазылушылар үшін

Аннотация

Two novel copper(II) complexes, Cu2L2(bipy) and Cu2L2(H2O)4·3H2O of Schiff base ligands derived from the condensation of L-tert-leucine and L-isoleucine with 2,4-dihydroxybenzaldehyde, are synthesized and characterized by single crystal X-ray diffraction. Compounds crystallize in the orthorhombic crystal system. The Cu2L2(bipy) complex has a distorted square planar geometry with an N2O2 coordination environment. Water is contained in supramolecular network pores. On the other hand, in the Cu2L2(H2O)4·3H2O complex, both copper atoms adopt a five-coordinated distorted square-pyramidal geometry with an NO4 coordination environment and guest water molecules form a 1D water chain. Both complexes build a 2D supramolecular network.

Авторлар туралы

D. Barut Celepci

Department of Physics, Faculty of Science

Хат алмасуға жауапты Автор.
Email: duygu.barut@deu.edu.tr
Түркия, İzmir

N. Korkmaz

Department of Chemistry, Faculty of Science

Email: duygu.barut@deu.edu.tr
Түркия, İzmir

S. Astley

Department of Chemistry, Faculty of Science

Email: duygu.barut@deu.edu.tr
Түркия, İzmir

M. Aygün

Department of Physics, Faculty of Science

Email: duygu.barut@deu.edu.tr
Түркия, İzmir

Қосымша файлдар

Қосымша файлдар
Әрекет
1. JATS XML

© Pleiades Publishing, Ltd., 2019