Email this article Binuclear Niobium Complex with Coordinated N-Heterocyclic Carbene
- Authors: Petrov P.A.1,2, Golubitskaya E.A.1,2, Kompankov N.B.1, Eltsov I.V.2, Sukhikh T.S.1,2, Sokolov M.N.1,2
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Affiliations:
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch
- Novosibirsk State University
- Issue: Vol 60, No 12 (2019)
- Pages: 1989-1994
- Section: Article
- URL: https://bakhtiniada.ru/0022-4766/article/view/162247
- DOI: https://doi.org/10.1134/S0022476619120151
- ID: 162247
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Abstract
By the interaction of Nb(NMe2)5 and 1,3-(2,6-diisopropylphenyl)imidazolium (IPr·HBF4) tetrafluoroborate a binuclear complex with coordinated N-heterocyclic carbene [(IPr)Nb(=NMe)(NMe2)(μ-F)2(μ-NMe2) NbF2(NMe2)] (1) is obtained. The reaction of Nb(NMe2)5 and 1,3-(2,4,6-trimethylphenyl)imidazolium (IMes·HBF4) tetrafluoroborate yields [(IMes)2H][NbF6] salt (2). The structure of the complexes is determined by single crystal X-ray diffraction.
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About the authors
P. A. Petrov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk State University
Author for correspondence.
Email: panah@niic.nsc.ru
Russian Federation, Novosibirsk; Novosibirsk
E. A. Golubitskaya
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk State University
Email: panah@niic.nsc.ru
Russian Federation, Novosibirsk; Novosibirsk
N. B. Kompankov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Email: panah@niic.nsc.ru
Russian Federation, Novosibirsk
I. V. Eltsov
Novosibirsk State University
Email: panah@niic.nsc.ru
Russian Federation, Novosibirsk
T. S. Sukhikh
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk State University
Email: panah@niic.nsc.ru
Russian Federation, Novosibirsk; Novosibirsk
M. N. Sokolov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk State University
Email: panah@niic.nsc.ru
Russian Federation, Novosibirsk; Novosibirsk
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