Crystal Structure of the Octahedral Rhenium Cluster Complex (Bu4N)4[Re6S8(OC6H4-p-NO2)6]


Cite item

Full Text

Open Access Open Access
Restricted Access Access granted
Restricted Access Subscription Access

Abstract

A cluster complex with the composition (Bu4N)4[Re6S8(CC6H4-p-NC2)6] having terminal phenoxide ligands is obtained by the reaction of (Bu4N)4[Re6S8Cl6] with silver p-nitrophenolate. The compound crystallizes in the orthorhombic space group Pccn with the following unit cell parameters: a = 19.507(2) Å, b = 31.645(3) Å, c = 19.237(2) Å, V = 19.237(2) Å3, Z = 4, dcalc = 1.774 g/cm3.

About the authors

S. Nagashima

Graduate School of Science and Engineering

Author for correspondence.
Email: nagasima@apc.saitama-u.ac.jp
Japan, Saitama

S. Kawada

Graduate School of Science and Engineering

Email: nagasima@apc.saitama-u.ac.jp
Japan, Saitama

H. Kobayashi

Graduate School of Science and Engineering

Email: nagasima@apc.saitama-u.ac.jp
Japan, Saitama

Supplementary files

Supplementary Files
Action
1. JATS XML

Copyright (c) 2019 Pleiades Publishing, Ltd.